"Ambush!" is the one Regiment-Order Catachan adds to the Voice of Command menu, and the sharpest blade in it. When an officer issues this Order to a friendly fighter that is set up hidden, that fighter immediately reveals and makes a shooting or melee attack with +1 to Hit, ignoring the target's cover — the spring of the trap, resolved before the enemy can react. It is the reward for the Regiment's patience: the hidden killer, held in the terrain across half the battle, loosed at the exact moment it hurts most.
Where Cadia keeps the full generic Order menu, Catachan trades that breadth for this single knife-edge. A Catachan Captain carries two Orders a round and a Sergeant one; an "Ambush!" spent well guts a target the foe believed was safe, then leaves the rest of the gang still unseen and still waiting.